Related Experiment Video
Updated: Jan 26, 2026

Decellularization of the Murine Cardiopulmonary Complex
Published on: May 30, 2021
Pentadiynylidyne and Pentacarbido Complexes
Anthony F Hill1, Richard A Manzano1
1Research School of Chemistry, The Australian National University, Canberra, ACT, 2601, Australia.
Abstract:
The reaction of the halocarbyne [W(≡CBr)(CO)2 (Tp*)] (Tp*=hydrotris(3,5-dimethylpyrazol-1-yl)borate) with trimethylsilyl-butadiyne, mediated by [Pd(PPh3 )4 ] and CuI, affords the first pentadiynylidyne complex [W(≡CC≡CC≡CSiMe3 )(CO)2 (Tp*)]. Desilylation provides a general route to heterobimetallic pentacarbido complexes, including [(Tp*)(CO)2 W(μ-C5 )(PPh3 )2 Ru(η-C5 H5 )] and [(Ph3 P)2 (CO)HIr{(μ-C5 )W(CO)2 (Tp*)}2 ].
Related Concept Videos
Protein Complex Assembly
Many viruses self-assemble into a fully functional unit using the infected host cell to...
Protein Complexes with Interchangeable Parts
The SCF ubiquitin ligase is a protein complex of five individual proteins. This complex attaches ubiquitin to other target proteins to mark them for degradation. In order...
Formation of Complex Ions
Complexation Equilibria: Factors Influencing Stability of Complexes
Complex Power
Complex power is defined as the multiplication of the voltage and the complex conjugate of the current. The magnitude of this power, known as apparent power, is measured in volt-amperes (VA). Notably, the angle of the complex power equates to the...
Crystal Field Theory - Octahedral Complexes
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...

