Acid Environment-improved fluorescence sensing performance: A quinoline Schiff base-containing sensor for Cd²⁺ with...

The development of acid environment-applicable fluorescence sensor is challenging but attractive topic, which can achieve the rapid and comprehensive evaluation of total soluble heavy metal content in natural water. In this work, a quinoline-containing Schiff base, AMQD, was utilized as fluorescence probe for Cd²⁺. Interestingly, the obtained chemosensor exhibited much better fluorescence detection sensitivity and selectivity toward Cd²⁺ in acidic 10% methanol aqueous solution (pH 4) comparing to those in neutral environment. Initially, the fluorescence emission of AMQD was almost invisible with the absence of metal ions, while a significant turn-on fluorescence response (~425 nm) can be observed with the addition of Cd²⁺. The fluorescence detection possesses excellent selectivity without the interference of any other metal cation. The recognition ratio between the fluorescence sensor AMQD and Cd²⁺ was confirmed to be 1:1, and the detection limit was calculated to be 2.4 nM.