Di-( m- m- m)terphenyl-Embedded Decaphyrin and Its Bis-Rh(I) Complex
Mainak Das1, B Adinarayana1, M Murugavel1
1School of Chemical Sciences , National Institute of Science Education and Research (NISER), HBNI , Bhubaneswar 752050 , Odisha , India.
Abstract:
A new rectangular-shaped carbadecaphyrin was successfully synthesized by introducing a terphenylene unit ( m- m- m) in the macrocyclic core. The terphenylene moiety offers an open framework with multiple binding pockets to stabilize two Rh(I) ions in the core. The photophysical and structural studies reveal the non-aromatic character of the ligand and its bis-Rh(I) complex.
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