Microstructure Evolution of Immiscible PP-PVA Blends Tuned by Polymer Ratio and Silica Nanoparticles

Composites of polypropylene (PP) and water soluble poly(vinyl alcohol) (PVA) can become an environmentally friendly precursor in preparing porous material, and their biphasic morphology needs to be manipulated. In this work, PP-PVA extrudates were prepared with a twin-screw extruder, and different PP/PVA ratios were employed to manipulate the morphology of the blends. Afterwards, different silicas were imbedded within the blends to further regulate the biphasic microstructure. PVA continuity, as a vital parameter in obtaining porous material, was determined by selective extraction measurement, and PP-PVA biphasic morphology was characterized by scanning microscopy analyses (SEM). Rheological measurement was also performed to correlate the microstructure evolution of the blends. First, it was found that with the increment of PVA proportion, PVA continuity is raised gradually, and the microstructure of blends containing 40⁻50 wt % of PVA is approaching co-continuous. Second, the localization of silicas was predicted based on the wettability of silica and polymers, and it was also confirmed by TEM that different silicas showed selective distribution. It is inspiring that R972 nanoparticles were found mainly distributed at the interface, which gives a possibility in preparing a surface-modified porous material. The shape distribution and average size of PVA nodules were examined by analyzing the SEM images. It is indicated that silicas with different wettabilities play disparate roles in tuning the biphasic microstructures, leading to heterogeneous PVA continuity.