Related Experiment Video
Updated: Jan 26, 2026

Determination of Aggregate Surface Morphology at the Interfacial Transition Zone ITZ
Published on: December 16, 2019
Parallel Tempering Monte Carlo Studies of Phase Transition of Free Boundary Planar Surfaces
Andrey Shobukhov1, Hiroshi Koibuchi2
1Faculty of Computational Mathematics and Cybernetics, Lomonosov Moscow State University, Leninskiye Gory, MSU, 2-nd Educational Building, Moscow 119991, Russia. shobukhov@cs.msu.su.
Abstract:
We numerically study surface models defined on hexagonal disks with a free boundary. 2D surface models for planar surfaces have recently attracted interest due to the engineering applications of functional materials such as graphene and its composite with polymers. These 2D composite meta-materials are strongly influenced by external stimuli such as thermal fluctuations if they are sufficiently thin. For this reason, it is very interesting to study the shape stability/instability of thin 2D materials against thermal fluctuations. In this paper, we study three types of surface models including Landau-Ginzburg (LG) and Helfirch-Polyakov models defined on triangulated hexagonal disks using the parallel tempering Monte Carlo simulation technique. We find that the planar surfaces undergo a first-order transition between the smooth and crumpled phases in the LG model and continuous transitions in the other two models. The first-order transition is relatively weak compared to the transition on spherical surfaces already reported. The continuous nature of the transition is consistent with the reported results, although the transitions are stronger than that of the reported ones.
Related Concept Videos
Phase Transitions
Phase Transitions: Sublimation and Deposition
Phase Transitions: Melting and Freezing
Phase Transitions: Vaporization and Condensation
Phase Diagrams
Crystal Field Theory - Tetrahedral and Square Planar Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...

