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Olefin Metathesis Polymerization: Ring-Opening Metathesis Polymerization (ROMP)01:16

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Dimensional analysis, also known as the factor label method, is a versatile approach for mathematical operations. The main principle behind this approach is: the units of quantities must be subjected to the same mathematical operations as their associated numbers. This method can be applied to computations ranging from simple unit conversions to more complex and multi-step calculations involving several different quantities and their units.
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Step-Growth Polymerization: Overview01:03

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Step-growth or condensation polymerization is a stepwise reaction of bi or multifunctional monomers to form long-chain polymers. As all the monomers are reactive, most of the monomers are consumed at the early stages of the reaction to form small chains of reactive oligomers, which then combine to form long polymer chains in the late stages. Hence, the reaction has to proceed for a long time to achieve high molecular weight polymers.
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Recently, the development of olefin metathesis polymerization advanced the field of polymer synthesis. Simply put, the reorganization of substituents on their double bonds between two olefins in the presence of a catalyst is known as the olefin metathesis reaction. The use of metathesis reaction for polymer synthesis is called olefin metathesis polymerization.
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Fabrication And Characterization Of Photonic Crystal Slow Light Waveguides And Cavities
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One-Dimensional Programmable Polymeric Microfiber Waveguide with Optically Reconfigurable Photonic Functions.

Hongyan Xia1, Junjie Cheng, Liangfu Zhu

  • 1Dongyuan Synergy Innovation Institute for Modern Industries of GDUT , Guangdong University of Technology , Guangzhou 510006 , P. R. China.

ACS Applied Materials & Interfaces
|April 10, 2019
PubMed
Summary
This summary is machine-generated.

Researchers developed programmable fluorescent micropatterns in polymer microfibers using tunable energy transfer. This enables reconfigurable photonic components like optical switches and logic gates, advancing optical communication and computing.

Keywords:
dynamic fluorescencefluorescence heterojunctionsprogrammable functionsreconfigurable photonic componentssingle polymeric waveguide

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Area of Science:

  • Photonics and Materials Science: Focus on programmable materials and reconfigurable photonic components.

Background:

  • Conventional reconfigurable photonic components often rely on mechanical deformation, limiting their practical applications.
  • Developing new methods for creating adaptable photonic devices is crucial for technological advancement.

Purpose of the Study:

  • To propose a novel strategy for fabricating programmable fluorescent micropatterns within single polymer microfibers.
  • To demonstrate the creation of reconfigurable photonic components using a tunable fluorescence resonance energy transfer (FRET) process.

Main Methods:

  • Designing and fabricating programmable fluorescent micropatterns in single polymer microfibers.
  • Utilizing a dynamically tunable fluorescence resonance energy transfer (FRET) process.
  • Achieving reconfigurable photonic components through optical stimuli.

Main Results:

  • Demonstrated a single polymeric waveguide microfiber capable of hosting multiple reconfigurable photonic components.
  • Successfully created optical switchable waveguide systems, photonic diodes, and transistors.
  • Enabled the writing, erasing, and rewriting of 1D binary patterns with external optical stimuli.

Conclusions:

  • The proposed FRET-based strategy offers a new pathway for designing and fabricating reconfigurable photonic devices.
  • These advancements hold significant potential for applications in highly integrated optical communication and optical computing.