Reactive Pad-Steam Dyeing of Cotton Fabric Modified with Cationic P(St-BA-VBT) Nanospheres

The Poly[Styrene-Butyl acrylate-(P-vinylbenzyl trimethyl ammonium chloride)] P(St-BA-VBT) nanospheres with N⁺(CH₃)₃ functional groups were successfully prepared and applied to modify cotton fabrics using a pad-dry process. The obtained cationic cotton fabrics were dyed with pad-steam dyeing with reactive dye. The results show that the appropriate concentration of nanospheres was 4 g/L. The sodium carbonate of 25 g/L and steaming time of 3 min were suitable for dyeing cationic cotton with 25 g/L of C.I. Reactive Blue 222. The color strength and dye fixation rates of dyed cationic cotton fabrics increased by 39.4% and 14.3% compared with untreated fabrics. Moreover, sodium carbonate and steaming time were reduced by 37.5% and 40%, respectively. The rubbing and washing fastness of dyed fabrics were equal or higher 3 and 4⁻5 grades, respectively. Scanning electron microscopy (SEM) images revealed that the P(St-BA-VBT) nanospheres randomly distributed and did not form a continuous film on the cationic cotton fiber surfaces. The X-ray photoelectron spectroscopy (XPS) analysis further demonstrated the presence of cationic nanospheres on the fiber surfaces. The cationic modification did not affect the breaking strength of cotton fabrics.