Related Experiment Video
Updated: Jan 26, 2026

Preparation of Polyoxometalate-based Photo-responsive Membranes for the Photo-activation of Manganese Oxide Catalysts
Published on: August 7, 2018
A Self-Assembled Organic/Metal Junction for Water Photo-Oxidation
Astrid J Olaya1, Terumasa Omatsu2, Jonnathan C Hidalgo-Acosta1
1Laboratory of Physical and Analytical Electrochemistry, EPFL Valais Wallis , École Polytechnique Fédérale de Lausanne , CH-1951 Sion , Switzerland.
Abstract:
We report the in situ self-assembly of TTF, TTF•+, and BF4- or PF6- into p-type semiconductors on the surface of Pt microparticles dispersed in water/acetonitrile mixtures. The visible light photoactivation of these self-assemblies leads to water oxidation forming O2 and H+, with an efficiency of 100% with respect to the initial concentration of TTF•+. TTF•+ is then completely reduced to TTF upon photoreduction with water. The Pt microparticles act as floating microelectrodes whose Fermi level is imposed by the different redox species in solution; here predominantly TTF, TTF•+, and HTTF+, which furthermore showed no signs of decomposition in solution.
Related Concept Videos
Metal-Semiconductor Junctions
Schottky Barriers
Schottky barriers arise when a metal with a work function (Φm) contacts a semiconductor with a different work function (Φs). Initially, electrons transfer until the Fermi levels of the metal and semiconductor align at equilibrium. For instance, if Φm > Φs, the semiconductor Fermi level is higher than the metal's before contact. The...
Biasing of Metal-Semiconductor Junctions
In Schottky junctions, where the semiconductor is n-type, applying a positive voltage to the metal relative to the semiconductor reduces its Fermi...
Oxidation and Reduction of Organic Molecules
The removal of an electron from a molecule, results in a...
Oxidation Numbers
Alkali Metals
Table 1: Properties of the alkali metals
Metal-Ligand Bonds
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...

