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Updated: Jan 26, 2026

The Effect of Interfacial Chemical Bonding in TiO2-SiO2 Composites on Their Photocatalytic NOx Abatement Performance
Published on: July 4, 2017
Efficient photocatalytic proton-coupled electron-transfer reduction of O2 using a saddle-distorted porphyrin as a
Emi Aoki1, Wataru Suzuki, Hiroaki Kotani
1Department of Chemistry, Faculty of Pure and Applied Sciences, University of Tsukuba and CREST (JST), 1-1-1 Tennoudai, Tsukuba, Ibaraki 305-8571, Japan. kojima@chem.tsukuba.ac.jp.
Abstract:
Photocatalytic O2 reduction reactions proceeded to produce H2O2 using a diprotonated saddle-distorted dodecaphenylporphyrin as a photocatalyst. The quantum yield (12%), the turnover number (3000 for 6 h), and the turnover frequency (500 h-1) are achieved in photocatalytic systems based on free-base porphyrins for the first time. The photocatalytic reaction mechanism has been revealed by ns-laser flash photolysis and kinetic analysis.
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