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Polymers02:34

Polymers

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The word polymer is derived from the Greek words “poly” which means “many” and “mer” which means “parts”. Polymers are long chains of molecules composed of repeating units of smaller molecules, known as monomers. They either occur naturally, such as DNA and proteins, or can be constructed synthetically, like plastics. They have varied structural characteristics, such as linear chains, branched chains, or complex networks, that contribute to the...
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Polymers02:34

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Electron Transport Chains01:28

Electron Transport Chains

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The final stage of cellular respiration is oxidative phosphorylation that consists of two steps: the electron transport chain and chemiosmosis. The electron transport chain is a set of proteins found in the inner mitochondrial membrane in eukaryotic cells. Its primary function is to establish a proton gradient that can be used during chemiosmosis to produce ATP and generate electron carriers, such as NAD+ and FAD, that are used in glycolysis and the citric acid cycle.
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Radical Chain-Growth Polymerization: Chain Branching01:17

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The skeletal structure of polymers synthesized via radical polymerization is always branched. For example, the polymerization of ethylene by radical polymerization results in a low-density grade of polyethylene with a heavily branched skeletal structure. Here, the radical site abstracts hydrogen from the growing chain, and the radical site shifts from the end (a primary carbon center) to anywhere within the growing chain (a secondary carbon center). Consequently, the part of the chain from the...
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Behavior of Concrete Under Compressive Load01:23

Behavior of Concrete Under Compressive Load

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Concrete exhibits specific behaviors under different compressive loads. Understanding this is crucial for understanding its structural integrity. When concrete undergoes uniaxial compression, it tends to develop cracks that run parallel to the direction of the force. These parallel cracks stem from localized tensile stresses that occur perpendicular to the compression direction. Additionally, angled cracks may appear due to the formation of shear planes.
As the concrete specimen fractures under...
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The Chain Rule01:30

The Chain Rule

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A system of interconnected gears provides a concrete physical interpretation of the Chain Rule in calculus. Consider three gears arranged in sequence, where the rotational speeds of the first, second, and third gears are represented by the variables x, z, and y, respectively. The first gear drives the second, and the second drives the third, so the motion of each gear depends on the one preceding it. This structure naturally leads to a two-stage variable relationship that can be analyzed using...
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Related Experiment Video

Updated: Jan 26, 2026

DNA Nanotubes as a Versatile Tool to Study Semiflexible Polymers
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Buckling a Semiflexible Polymer Chain under Compression.

Ekaterina Pilyugina1,2, Brad Krajina3, Andrew J Spakowitz4,5,6,7

  • 1Center for Molecular Study of Condensed Soft Matter, Illinois Institute of Technology, Chicago, IL 60616, USA. kattisse@gmail.com.

Polymers
|April 12, 2019
PubMed
Summary
This summary is machine-generated.

Fluctuating polymers require more force to buckle than non-fluctuating rods. Chain entropy favors the extended state, making the buckling transition more gradual due to Brownian motion.

Keywords:
elasticityfluctuationssemiflexible polymers

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Area of Science:

  • Soft matter physics
  • Polymer physics
  • Statistical mechanics

Background:

  • Structural transitions like buckling are crucial in molecular dynamics.
  • Traditional buckling theories neglect Brownian fluctuations significant in polymers.
  • Existing models offer conflicting predictions on fluctuation effects on buckling force.

Purpose of the Study:

  • To analyze the buckling of a fluctuating semiflexible polymer under compressive load.
  • To provide unambiguous predictions for buckling conditions using exact polymer statistics.
  • To elucidate the thermodynamic contributions to the buckling transition.

Main Methods:

  • Utilizing exact results for the statistical behavior of the worm-like chain model.
  • Analyzing thermodynamic contributions to understand the role of chain entropy.
  • Comparing buckling behavior with and without fluctuations.

Main Results:

  • A fluctuating polymer requires a higher critical force to buckle compared to a non-fluctuating elastic rod.
  • The buckling transition changes from second order to a more gradual, compliant transition with fluctuations.
  • Chain entropy thermodynamically favors the extended state, justifying the elevated buckling force.

Conclusions:

  • Brownian fluctuations significantly alter polymer buckling behavior.
  • The worm-like chain model provides accurate predictions for fluctuating polymer buckling.
  • Understanding these transitions is vital for macromolecular chains and biomaterials.