A Peanut-Shaped Polyaromatic Capsule: Solvent-Dependent Transformation and Electronic Properties of a Non-Contacted...

Synthesis of molecular containers capable of incorporating multiple fullerenes remains challenging. Reported here is that room-temperature mixing of metal ions with W-shaped bispyridine ligands featuring polyaromatic panels results in the quantitative formation of a peanut-shaped M₂ L₄ capsule. The capsule reversibly converts into two molecules of an ML₂ double tube in response to changes in the solvent. Notably, the capsule allows the incorporation of two fullerene molecules into the connected two spherical cavities at room temperature. The close proximity yet non-contact of the encapsulated C₆₀ molecules, with a separation of 6.4 Å, was revealed by X-ray crystallographic analysis. The resultant, unusual fullerene dimer undergoes sequential reduction within the capsule to generate (C₆₀ ^.- )₂ , C₆₀ ^.- ⋅C₆₀ ^2- , and (C₆₀ ^2- )₂ species. Furthermore, temperature-controlled stepwise incorporation of two C₆₀ molecules into the capsule is demonstrated.