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Preferential synthesis of ethanol from syngas via dimethyl oxalate hydrogenation over an integrated catalyst
Xin Shang1, Huijiang Huang, Qiao Han
1Key Laboratory for Green Chemical Technology of Ministry of Education, Collaborative Innovation Center of Chemical Science and Engineering, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China. yujunzhao@tju.edu.cn.
Abstract:
An integrated catalyst that contains Fe5C2 and CuZnO-SiO2 with a dual-bed configuration was designed for the preferential synthesis of ethanol via dimethyl oxalate hydrogenation. The cooperation of the two catalyst components remarkably inhibited the formation of various byproducts, resulting in a significantly high ethanol yield of about 98%.
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