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Isotopes01:12

Isotopes

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Elements have a set number of protons that determines their atomic number (Z). For example, all atoms with eight protons are oxygen; however, the number of neutrons can vary for atoms of the same element. The sum of the number of protons and the number of neutrons is the mass number (A). Atoms with the same atomic number but different mass numbers are called isotopes. Elements can have multiple isotopes, for example, carbon-12, carbon-13, and carbon-14.
An element's atomic mass, or weight,...
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Elements: Chemical Symbols and Isotopes02:31

Elements: Chemical Symbols and Isotopes

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A chemical symbol is an abbreviation used to indicate an element or an atom of an element. For example, the symbol for mercury is Hg. The same symbol is used to indicate one atom of mercury (microscopic domain) or to label a container of many atoms of the element mercury (macroscopic domain).
Some symbols are derived from the common English name of the element; others are abbreviations of the name in another language — Latin, Greek or German. For example, the symbol for aluminum (common name)...
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Transcription Attenuation in Prokaryotes02:42

Transcription Attenuation in Prokaryotes

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Transcriptional attenuation occurs when RNA transcription is prematurely terminated due to the formation of a terminator mRNA hairpin structure.  Bacteria use these hairpins to regulate the transcription process and control the synthesis of several amino acids including histidine, lysine, threonine, and phenylalanine. Transcription attenuation takes place in the non-coding regions of mRNA.
There are several different mechanisms used to attenuate transcription. In ribosome mediated...
18.2K
Isotopes and Radioisotopes01:28

Isotopes and Radioisotopes

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In the early 1900s, English chemist Frederick Soddy realized that an element could have atoms with different masses that were chemically indistinguishable. These different types are called isotopes — atoms of the same element that differ in mass. Isotopes differ in mass because they have different numbers of neutrons but are chemically identical because they have the same number of protons. Soddy was awarded the Nobel Prize in Chemistry in 1921 for this discovery.
An isotope containing...
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Mass Spectrometry: Isotope Effect01:13

Mass Spectrometry: Isotope Effect

4.0K
Most elements exist in nature as a mixture of isotopes. The isotopes differ in weight due to their respective number of neutrons. The molecular weight of a molecule is different depending on the specific isotope of its elements involved. As a result, the mass spectrum of the molecule exhibits peaks from the same fragment at multiple positions. The positions of these mass signals depend on the mass differences between isotopes. Furthermore, the intensity of these signals is dependent on the...
4.0K
Gene-Environment Interactions01:20

Gene-Environment Interactions

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Gene expression is a dynamic process that is significantly influenced by environmental factors. This interaction underlies the complex nature of biological development and the phenotypic differences observed among individuals, even among those with identical genetic makeups. Factors such as radiation, temperature, behavior, nutrition, and stress play pivotal roles in determining how genes are expressed. The concept of the reaction range is central to understanding this interaction. It posits...
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Updated: Jan 26, 2026

Using Laser Scanning Microscopy to Determine Electromigration in Molybdenum Disilicide
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Using Laser Scanning Microscopy to Determine Electromigration in Molybdenum Disilicide

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Tracing Molybdenum Attenuation in Mining Environments Using Molybdenum Stable Isotopes.

Elliott K Skierszkan1, Jared M Robertson2,3, Matthew B J Lindsay2

  • 1Lorax Environmental Services Ltd. , 2289 Burrard Street , Vancouver , BC Canada , V6J 3H9.

Environmental Science & Technology
|April 19, 2019
PubMed
Summary

Molybdenum (Mo) mobility in mine wastes is controlled by sorption onto iron (oxyhydr)oxides in oxic environments. Molybdenum stable isotope (δ⁹⁸/⁹⁵Mo) analyses effectively trace these attenuation processes.

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Area of Science:

  • Environmental Science
  • Geochemistry
  • Isotope Geochemistry

Background:

  • Molybdenum (Mo) contamination in mining regions poses environmental risks.
  • Understanding Mo mobility in mine wastes is crucial for water quality management.
  • Tailings Management Facilities (TMFs) present complex geochemical environments.

Purpose of the Study:

  • Investigate geochemical controls on Mo mobility in a TMF.
  • Utilize Mo stable isotopes (δ⁹⁸/⁹⁵Mo) to trace attenuation processes.
  • Integrate isotopic data with mineralogical and aqueous chemistry.

Main Methods:

  • Molybdenum stable isotope (δ⁹⁸/⁹⁵Mo) analyses.
  • X-ray absorption spectroscopy (XAS).
  • X-ray diffraction (XRD), Raman spectroscopy, transmission electron microscopy (TEM).
  • Aqueous chemical analyses.

Main Results:

  • Dissolved Mo concentrations correlated inversely with δ⁹⁸/⁹⁵Mo values, indicating attenuation.
  • Inner-sphere complexation of Mo(VI) with ferrihydrite was a primary Mo removal mechanism with ~1‰ isotope fractionation.
  • Mo attenuation and isotope fractionation were limited in anoxic seepage but enhanced upon oxidation and sorption to Fe-(oxyhydr)oxides in a pond.

Conclusions:

  • Sorption onto Fe-(oxyhydr)oxides is a key process for attenuating Mo in oxic mine waste environments.
  • Mo stable isotope analyses serve as a valuable tracer for Mo attenuation processes.
  • Geochemical conditions, particularly redox state and Fe-(oxyhydr)oxide presence, significantly influence Mo mobility.