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Reduced-Dimensional Perovskite Enabled by Organic Diamine for Efficient Photovoltaics
Tingting Niu1, Hui Ren1, Bo Wu2
1Key Laboratory of Flexible Electronics (KLOFE) and Institute of Advanced Materials (IAM), Jiangsu National Synergistic Innovation Center for Advanced Materials (SICAM) , Nanjing Tech University (NanjingTech) , 30 South Puzhu Road , Nanjing 211816 , P. R. China.
Abstract:
Reduced-dimensional (RD) perovskite solar cells (PSCs) are emerging as highly attractive alternatives to three-dimensional (3D) PSCs due to their dramatically improved environmental stability and photostability. Diamine-based RD perovskites with a single organic amine interlayer possess orderly inorganic sheets and a smaller insulation area, indicating great potential in combining high efficiency and long-term stability. Here, we report an efficient and stable RD PSC based on 1,4-butanediamine (BDA). We found that the BDA-based RD perovskite exhibits improved crystallinity, reduced trap-state densities, and enhanced charge mobility compared to those of butylamine (BA)-based RD (BA-RD) perovskite. A high power conversion efficiency of 17.91% was achieved with negligible hysteresis. Moreover, the device showed improved stability compared to those of BA-RD and 3D films and devices. The findings may inspire new developments in introducing organic diamine for efficient and stable RD PSCs.
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