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Updated: Jan 25, 2026

Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
Published on: June 7, 2018
Thermoinduced structural-transformation and thermochromic luminescence in organic manganese chloride crystals
Meng-En Sun1, Yao Li1, Xi-Yan Dong1,2
1College of Chemistry and Molecular Engineering , Zhengzhou University , Zhengzhou 450001 , China .
Abstract:
The [Mn2Cl9]5- mode of red emissive (C4NOH10)5Mn2Cl9·C2H5OH under thermal treatment will be cleaved into [MnCl4]2- in the green emissive (C4NOH10)2MnCl4 with the departure of ethanol. The rapid conversion of luminescence from red to green provides new insight into the luminescence origin and thermal stability of organic-inorganic metal halide hybrids.
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