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Published on: August 18, 2020
Palladium/Norbornene Cooperative Catalysis
Jianchun Wang1, Guangbin Dong1
1Department of Chemistry, University of Chicago, Chicago, Illinois 60637, United States.
Abstract:
Palladium/norbornene cooperative catalysis has emerged as a distinct approach to construct polyfunctionalized arenes from readily available starting materials. This Review provides a comprehensive overview of this field, including the early stoichiometric investigations, catalytic reaction developments, as well as the applications in the syntheses of bioactive compounds and polymers. The section of catalytic reactions is divided into two parts according to the reaction initiation mode: Pd(0)-initiated reactions and Pd(II)-initiated reactions.
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