Rapid and Low-Cost Electrochemical Synthesis of UiO-66-NH₂ with Enhanced Fluorescence Detection Performance

Rapid and low-cost synthesis of metal-organic frameworks (MOFs) are very meaningful for their future practical application. In the present study, a Zr-based ultrastable MOF, UiO-66-NH₂, was successfully synthesized by electrochemical method using metal Zr as the metal source at room temperature and atmospheric pressure. The effects of the reaction conditions, including the ratio of solvent (electrolyte), the applied voltage and different reaction time, on the crystallinity, morphology, and synthesis rate of the product were fully investigated. The results confirm that electrochemically synthesized UiO-66-NH₂ under the optimized condition possesses apparent merits such as high crystallinity, uniform morphology and high porosity. Moreover, the electrochemical synthesis method of UiO-66-NH₂ is promising for the large-scale and economical synthesis of nanoscale product to gramme degree. Interestingly, the resulting UiO-66-NH₂ synthesized by this electrochemical method exhibits more excellent performance for the fluorescence detection of Fe³⁺ ions in water (detection limit of 10^-8 mol/L) than that of the material prepared by solvothermal method.