Solid solution formation in the metatorbernite-metazeunerite system (Cu(UO2)2(PO4)2- x(AsO4) x. nH2O) and their

Joanna Kulaszewska1, Sandra Dann1, Peter Warwick1

  • 11 Department of Chemistry, Loughborough University , Loughborough LE11 3TU , UK.

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All meta-directing substituents are deactivating groups. These substituents withdraw electrons from the aromatic ring, making the ring less reactive toward electrophilic substitution. For example, the nitration of nitrobenzene is 100,000 times slower than that of benzene because of the deactivating effect of the nitro group. The first step in an electrophilic aromatic substitution is the addition of an electrophile to form a resonance-stabilized carbocation. The energy diagrams for...
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