SPECIATION OF IODINE IN SOIL SOLUTION IN FOREST AND GRASSLAND SOILS IN ROKKASHO, JAPAN

The behaviour of I in soil depends on its chemical form in soil solution. Stable I (127I) in the soil solution under actual soil conditions was investigated as a natural analogue of long-lived radioiodine (129I). Soil samples were collected at 5-cm depth intervals down to 20 cm from forests and grasslands in Rokkasho, where the Japanese first commercial nuclear fuel reprocessing plant is located, and the soil solution was extracted by centrifugation. Almost half of total I in the soil solution was iodide, and the other half was dissolved organic I (DOI), with iodate under the detection limit. The proportion of DOI in total I at 0-5 cm depth was larger than the proportions at 5-20 cm depth. The concentration of DOI was positively correlated with that of DOC in the soil solution, suggesting that the behaviour of DOI in the surface soil is affected by labile organic matter dynamics.