Ammonia Volatilization Loss and Corn Nitrogen Nutrition and Productivity with Efficiency Enhanced UAN and Urea under...

New urease and nitrification inhibitors and polymer coatings were introduced in recent years, but their effects on N loss and plant N nutrition were scarcely examined in agronomic no-tillage production systems. A field experiment of urea treated with efficiency enhancers was conducted on no-tillage corn (Zea mays L.) in Tennessee, the USA during 2013-2015. A field experiment on urea and ammonium nitrate (UAN) treated with efficiency enhancers was carried out on no-tillage corn in Tennessee in 2014 and 2015. Urea treated with N-(n-butyl) thiophosphoric triamide (NBPT) at concentrations of 20% (NBPT₁), 26.7% (NBPT₂), or 30% (NBPT₃) and polymer coated urea (PCU) were effective but maleic-itaconic copolymer treated urea was ineffective in reducing ammonia volatilization loss and improving N nutrition, grain yield, and N agronomic use efficiency of corn compared with untreated urea. Specifically, NBPT₁, NBPT₂, or NBPT₃ treated urea and PCU reduced the total ammonia volatilization loss by 29.1-78.8%, 35.4-81.9%, 77.3-87.4%, and 59.1-83.3% during the 20 days after N applications, but increased grain yield by 15.6-31.4%, 12.9-34.8%, 18.7-19.9%, and 14.6-41.1%, respectively. The inhibitory effect of NBPT on ammonia volatilization did not improve with NBPT concentration increased from 20% to 30%. UAN treated with NBPT₃ or a combination of urease and nitrification inhibitors resulted in 16.5-16.6% higher corn yield than untreated UAN only when they were surface applied. In conclusion, when urea-containing fertilizers are surface applied without any incorporation into the soil under no-tillage, their use efficiencies and performances on corn can be enhanced with an effective urease inhibitor in areas and years with noticeable urea N losses.