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Updated: Jan 25, 2026

Application of a Coupling Agent to Improve the Dielectric Properties of Polymer-Based Nanocomposites
Published on: September 19, 2020
DIELECTRIC PROPERTIES OF POLY (VINYLIDENE FLUORIDE)/BARIUM TITANATE NANOCOMPOSITES UNDER GAMMA IRRADIATION
K Waree1, K Pangza2, N Jangsawang2
1Department of Physics, Faculty of science, Khon Kaen University, Khon Kaen, Thailand.
Abstract:
The main focus of this study is to investigate the effect of gamma irradiation on the electrical properties of PVDF/BT nanocomposites. A 1.25 MeV gamma-ray was delivered to the composite films with different BaTiO3-volume fraction, ƒBT = 0-0.4, and with different absorbed doses ranged 50-2500 Gy. Dielectric properties of PVDF/BaTiO3 composites under frequencies ranged from 100 Hz to 10 MHz at room temperature were investigated using an impedance analyser. An increase of 28% in the dielectric constant and a decrease of 15% in the loss tangent were observed in the PVDF/BT 40 vol% nanocomposite film under the accumulated dose of 1500 Gy. Scanning electron microscopy provided no significant difference in microscopic structures between non-exposed and gamma-exposed materials. Fourier-transform infra-red spectroscopy provides gamma-induced transition of PVDF-crystalline forms as alpha-PVDF into beta-PVDF/gamma-PVDF which has been reported as one of the main factors affected the change of dielectric constant in polymers. UV-visible spectrophotometry has been observed gamma-induced red shift in the absorption edge of the PVDF/BT 40 vol% nanocomposite film from 400 nm to 420 nm under the accumulated dose of 1500 Gy. However, a blue shift is observed with increase the accumulated dose up to 2000 Gy.
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