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Published on: December 17, 2018
Tracking legacy mercury in the Hackensack River estuary using mercury stable isotopes
John R Reinfelder1, Sarah E Janssen2
1Department of Environmental Sciences, Rutgers University, 14 College Farm Road, New Brunswick, NJ 08901 United States.
Legacy mercury (Hg) contamination in the Hackensack River estuary is being redistributed. Mercury stable isotopes reveal that Berry's Creek is a significant source, impacting downstream and marsh habitats.
Area of Science:
- Environmental Science
- Geochemistry
- Ecotoxicology
Background:
- Estuarine ecosystems often retain legacy mercury (Hg) contamination from historical industrial activities.
- Understanding mercury's spatial redistribution is crucial for assessing ecological risks and informing remediation strategies.
Purpose of the Study:
- To investigate the spatial redistribution of legacy mercury contamination in the Hackensack River estuary using mercury stable isotopes.
- To quantify the contribution of historical mercury sources, specifically Berry's Creek, to the overall mercury burden in the estuary.
Main Methods:
- Analysis of total mercury (Hg) concentrations in sediment samples from the Hackensack River estuary and Berry's Creek.
- Measurement of mercury stable isotopes (δ²⁰²Hg) to trace mercury sources and pathways.
- Application of an isotope mixing model to estimate mercury contributions from different sources.
Main Results:
- Total Hg concentrations varied significantly, with higher levels found in Berry's Creek compared to the main Hackensack River estuary.
- Mercury stable isotope values (δ²⁰²Hg) showed distinct patterns, with the highest values originating from upper Berry's Creek.
- The isotope mixing model estimated that Berry's Creek contributes a substantial proportion (21%-82%) of the mercury found in the Hackensack River estuary sediments.
Conclusions:
- Mercury stable isotopes are effective tools for tracking the redistribution of mercury in tidal ecosystems.
- Legacy mercury from Berry's Creek significantly contaminates the Hackensack River estuary, affecting even remote marsh habitats.
- Estuarine ecosystems can experience widespread mercury redistribution from localized historical contamination sources.
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