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Updated: Jan 25, 2026

Single-molecule Manipulation of G-quadruplexes by Magnetic Tweezers
Published on: September 19, 2017
Correlating blocking temperatures with relaxation mechanisms in monometallic single-molecule magnets with high energy
Marcus J Giansiracusa1, Andreas K Kostopoulos1, David Collison1
1The School of Chemistry, The University of Manchester Oxford Road, Manchester, M13 9PL, UK. richard.winpenny@manchester.ac.uk nicholas.chilton@manchester.ac.uk.
Abstract:
We report an empirical correlation between the blocking temperature of large energy barrier SMMs and the relaxation time at the point where the Raman and Orbach relaxation mechanisms have the same rate; this supports the idea that the ability to retain magnetisation is controlled by the Raman relaxation process in these materials.
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