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Oxidative addition of elemental selenium to 1,4,2,5-diazadiborinine
Gillian Kor Hwee Goh1, Yongxin Li, Rei Kinjo
1Division of Chemistry and Biological Chemistry (CBC), Nanyang Technological University (NTU), 21 Nanyang Link, 637371 Singapore. rkinjo@ntu.edu.sg.
Abstract:
Annulated 1,4,2,5-diazadiborinine 3 has been synthesized and fully characterized. Computational studies revealed that compound 3 features a relatively small HOMO-LUMO gap (2.61 eV). When 3 was treated with elemental grey selenium (Se), oxidative addition of Se proceeded regioselectively at the boron centres of 3 to give a bicyclo[2.2.2] molecule 4 involving a B-Se-Se-B unit, which can be deemed a heavier analogue of dibora-peroxide.
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