Related Experiment Video
Updated: Jan 25, 2026

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
Published on: March 20, 2017
Accessing the First nido-Carborane-Substituted Diphosphetane: A Ligand and Synthon for nido-Carboranylphosphanes
Peter Coburger1, Pavlo Bielytskyi2, Darcy Williamson1,3
1Leipzig University, Faculty of Chemistry and Mineralogy, Institute of Inorganic Chemistry, Johannisallee 29, 04103, Leipzig, Germany.
Abstract:
Deboronation of a carborane-substituted diphosphetane 2 in toluene yielded the first nido-carboranyldiphosphetane 1. The P-P bond in 1 can be broken via dismutation reactions with diaryl dichalcogenides yielding nido-carboranyl bis-phosphanes that were not accessible via established synthetic protocols. Additionally, transition metal complexes of 1 could be isolated including one coordination polymer. Notably, when the deboronation of 2 is carried out in ethanol, unprecedented nido-carborane-substituted secondary bis-phosphane monoxides (3, 4) are obtained. These compounds are interesting starting materials for further reactivity studies due to their P-H bonds. Experimental findings are supported by DFT calculations including the calculation of reaction mechanisms and NMR spectroscopic parameters.
Related Concept Videos
Ligand Binding Sites
Protein-ligand interactions are quite specific; even though numerous potential ligands surround a cellular protein at any given time, only a particular ligand can bind to that protein. Moreover, a ligand binds only to a dedicated area on the surface of the protein, known as the...
Ligand Binding Sites
Metal-Ligand Bonds
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
Ligand Binding and Linkage
Ligand Binding and Linkage
Diazonium Group Substitution: –OH and –H

