Core-shell Fe₃O₄@Au nanocomposite as dual-functional optical probe and potential removal system for arsenic (III)...

We report for the very first time, development of a dual functional nanocomposite to perform as an optical probe as well as removal system for As(III) from ground water. Upon suitable thiolation using dithiothreitol (DTT), the Fe₃O₄(core)-Au(shell) nanocomposite (DTT-Fe₃O₄@Au) has been fabricated that can detect As(III) in aqueous solution with significantly low limit of detection and holds potential for selective removal of As(III) from water owing to its magnetic core. Due to high affinity of -SH groups for As(III), the nanoparticles undergo aggregation in the presence of As(III), resulting in a significant decrease in absorbance, yielding the limit of detection (LOD) as 0.86 ppb, which is much lower than the World Health Organisation (WHO) recommended threshold value of 10 ppb. UV-vis spectroscopy in conjunction with dynamic light scattering and electron microscopy techniques have further elaborated the detailed interaction between As(III) and DTT-Fe₃O₄@Au nanocomposite regarding their size dynamics and solution behaviour during the interaction. Moreover, ca.70% removal of As(III) from aqueous solution by DTT-Fe₃O₄@Au has been observed by ICP-MS measurement strengthening the potential of this nanocomposite as a dual-functional probe and filter.