Ascorbic acid induced activation of persulfate for pentachlorophenol degradation

In the present study, ascorbic acid (AA) induced persulfate activation was investigated for the further exploration of organic pollutants oxidation by persulfate. We interestingly found that AA showed a significant catalytic activity to persulfate. Under neutral pH and room temperature condition, about 71.3% of pentachlorophenol (PCP, 10 mg L^-1) was decomposed in 180 min with 40 mmol L^-1 persulfate and 1.0 mmol L^-1 AA, while only 15.4% and 3.2% of PCP was removed by alone persulfate and AA respectively. The result of EPR spectra identified sulfate radical (SO₄^•-) and hydroxyl radical (OH) were generated during the reaction between persulfate and AA. Quenching experiments confirmed that both SO₄^- and OH contributed to the decomposition of PCP. With the addition of AA augmented from 0 to 1 mmol L^-1, the PCP degradation ratio continuously increased. However, excess AA could consume the generated reactive oxygen species (ROSs) that led to the inhibition of PCP degradation. Meanwhile, the PCP degradation by persulfate-AA was strongly pH dependent. The PCP degradation rate was declined as the initial pH increased from 3.5 to 10.5. At pH above 12.5, the base activation began to predominate over AA activation of persulfate. Furthermore, it was observed that the AA inducing persulfate activation was related to the extent of AA ionization, while C₆H₈O₆ promoted the highest persulfate activation for the PCP degradation, and C₆H₆O₆^2- induced the lowest persulfate activation. This study indicates the high potential of AA induced persulfate activation for treatment of organochlorine contaminated water.