Iodine encapsulated in mesoporous carbon enabling high-efficiency capacitive potassium-Ion storage

The development of potassium-ion batteries (KIBs) are hampered by the lack of appropriate electrode materials allowing for the reversible insertion/de-insertion of the large K-ion. Iodine, as a conversion-type cathode for rechargeable batteries, has high theoretical capacity and excellent electrochemical reversibility, making it a potential cathode material for KIBs. However, due to the defects of iodine with the poor electronic conductivity and easy dissolution in the electrolyte, an intensive quest for iodine-based KIBs enabling high-performance potassium-ion storage is still underway. In this work, a high-efficiency capacitive K-I₂ battery has been successfully achieved by constructing a nanocomposite of iodine encapsulated in mesoporous carbon (CMK-3). The as-prepared CMK-3/iodine nanocomposite exhibites excellent rate performance (89.3 mA h g^-1 at 0.5 A g^-1) and superior cycling stability, which remarkably exceeds most of reported KIBs cathode materials. Such a excellent electrochemical performance can be ascribed to the engineered structure of CMK-3/iodine hybridized electrode which can alleviate the impact of the shuttle phenomenon, improve electronic conductivity and facilitate ion diffusion. As a consequence, iodine within the conductive protecting CMK-3 can afford an extraordinary pseudo-capacitive potassium-ion storage, which sheds light on the development prospect of conversion-type electrode materials to meet urgent demand for advanced KIBs.