Sustainable hydrophilization to separate hazardous chlorine PVC from plastic wastes using H₂O₂/ultrasonic irrigation

Polyvinyl chloride (PVC) products comprise a large portion of plastic wastes and cause severe environmental burdens in thermal recycling such as toxic release and disposal difficulties. Selective separation methods for PVC containing hazardous chlorine are required for the development of suitable disposal or material recycling processes. However, separating PVC selectively from municipal plastic waste mixtures is difficult due to their similar hydrophobic surface and appearance densities. This study presents a one-step, selective separation technique for PVC using H₂O₂ solution under ultrasonic irrigation to promote the selective development of hydrophilicity only on the PVC surface. The combined treatment helped to decrease air bubbles attached on the PVC surface because of increased wettability, which allowed the treated PVC to settle on the bottom of the flotation reactor. However, the remaining plastic wastes were easily floated off because they maintained their hydrophobicity. The combined treatment with a low concentration of 3% H₂O₂ and ultrasonic irrigation for 30 min afforded 100% purity and recovery of the PVC separated from the municipal plastic waste mixture. This proposed treatment is therefore a promising and inexpensive way to improve plastic recycling quality through selective PVC separation by the selective development of hydrophilicity on its surface.