Bi₄O₅I₂/nitrogen-doped hierarchical carbon (NHC) composites with tremella-like structure for high photocatalytic...

BiOI is a visible photocatalyst towards organic pollutant. In this work, biomass waste (withered typha grass) was used to fabricate nitrogen-doped hierarchical carbon (NHC) by an one-step carbonization route. Then NHC provided a good carrier to load the BiOI semiconductor materials by a green simple co-precipitation method, after adding NaOH solution, the irregular microspheres BiOI/NHC was gradually etched by OH^- to form the tremella-like Bi₄O₅I₂/NHC. The well-defined tremella-like Bi₄O₅I₂/NHC invested adequate interface and high particular surface range (S_BET: 66 m² g^-1), which is higher than pure BiOI (22 m² g^-1) and Bi₄O₅I₂ (17 m² g^-1). Multiple synergistic effects, such as high S_BET can give more dynamic destinations, the special tremella-like structure can assimilate more reflected occurrence light of other nanosheets, low I content can increase the conduction/valence band gap of semiconductor materials and NHC can act as an electron acceptor, making as-prepared Bi₄O₅I₂/NHC composite ideal candidates for photocatalysis. The degradation rate of Bi₄O₅I₂/NHC reaches up to 87.4% of methyl orange in 2 h, which is about 2 times higher than BiOI and Bi₄O₅I₂. Therefore, this work gives a technique to link NHC derived from biomass waste to Bi₄O₅I₂ with highly-efficiency photocatalytic performance.