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An Azido-Cyanide Mixed-Bridged [Fe4Ni4] Single-Molecule Magnet
Jiong Yang1, Yi-Fei Deng1, Xin-Yu Zhang1
1Department of Chemistry , Southern University of Science and Technology , Shenzhen , 518055 , China.
Abstract:
Taking advantages of both azide and cyanide bridges in magnetism and synthesis, an azido-cyanide mixed-bridged octanuclear [FeIII4NiII4] SMM of [{(enbzpy)Ni2(μ1,1-N3)2·(DMF)}{Tp*Fe(CN)3}2]2·2DMF·14H2O (1) was explored and characterized, which exhibits slow relaxation of the magnetization and an S = 6 ground state benefit from the end-on azido bridges.
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