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Updated: Jan 25, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
Reversible insertion of CO into an aluminium-carbon bond
Richard Y Kong1, Mark R Crimmin
1Department of Chemistry, Molecular Sciences Research Hub, Imperial College London, 80 Wood Lane, Shepherds Bush, London, W12 0BZ, UK. m.crimmin@imperial.ac.uk.
Abstract:
A [2.2.1] aluminium metallobicycle is capable of reversibly inserting CO to form a [2.2.2] metallobicycle at 100 °C. Computational studies reveal a highly asynchronous, but concerted, transition state for CO insertion. The coordination of CO to aluminium precedes C-C bond formation. The reversible migratory insertion of CO at aluminium thus mimics well-established transition-metal reactivity.
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