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Updated: Jan 24, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
Metal-organic framework nanosheets with flower-like structure as probes for H2S detection and in situ singlet-oxygen
Pinghua Ling1, Caihua Qian, Jinjin Yu
1Laboratory of Functionalized Molecular Solids, Ministry of Education, Anhui Key Laboratory of Chemo/Biosensing, College of Chemistry and Materials Science, Anhui Normal University, Wuhu 241002, P. R. China. phling@ahnu.edu.cn fgao@mail.ahnu.edu.cn.
Abstract:
Herein, a novel bifunctional flower-like metal-organic framework (MOF) was designed as a probe, which could be activated by H2S, induce itself disassembly and then release linker, Zn porphyrin. Therefore, the fluorescence of the system is enhanced and 1O2 could be produced in situ, opening up a new avenue for selective H2S detection under physiological pH and controllable 1O2 release.
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