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Oxygen-Bridged Ga2 (Et)3 (OTeF5 )3 and the Weakly Coordinating Anions [Ga(Et)(OTeF5 )3 ]- and [Ga(OTeF5 )4 ]
Anja Wiesner1, Lukas Fischer1, Simon Steinhauer1
1Fachbereich Biologie, Chemie, Pharmazie, Institut für Chemie und Biochemie-Anorganische Chemie, Freie Universität Berlin, Fabeckstrasse 34/36, 14195, Berlin, Germany.
Abstract:
Salts of the weakly coordinating anions [Ga(OTeF5 )4 ]- as well as [Ga(Et)(OTeF5 )3 ]- and the neutral Ga2 (Et)3 (OTeF5 )3 were synthesized and characterized by spectroscopic methods and single-crystal X-ray diffraction. Ga2 (Et)3 (OTeF5 )3 was formed by treating GaEt3 with pentafluoroorthotelluric acid (HOTeF5 ) and reacted with PPh4 Cl and CPh3 Cl to [PPh4 ][Ga(Et)(OTeF5 )3 ] and [CPh3 ][Ga(Et)(OTeF5 )3 ]. In contrast, Ag[Ga(OTeF5 )4 ] was prepared from AgOTeF5 and GaCl3 and was used as a versatile starting material for further reactions. Starting with Ag[Ga(OTeF5 )4 ] the substrates [PPh4 ][Ga(OTeF5 )4 ] and [CPh3 ][Ga(OTeF5 )4 ] were formed from PPh4 Cl and CPh3 Cl.
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