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Updated: Jan 24, 2026

Two-way Valorization of Blast Furnace Slag: Synthesis of Precipitated Calcium Carbonate and Zeolitic Heavy Metal Adsorbent
Published on: February 21, 2017
Meso-/microporous carbon as an adsorbent for enhanced performance in solid-phase microextraction of chlorobenzenes
Hu Cheng1, Yang Song1, Yongrong Bian1
1Key Laboratory of Soil Environment and Pollution Remediation, Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008, PR China; University of Chinese Academy of Sciences, Beijing 100049, PR China.
Abstract:
There is urgent demand for the design of advanced coating materials for solid-phase microextraction (SPME) for water quality monitoring and assessment because of the global occurrence of chlorobenzenes (CBs). In this study, we proposed a dual-order activation method in which potassium hydroxide is used to modify pre-activated calcium citrate to synthesize a highly developed meso-/microporous carbon (MMC). The as-obtained MMC presented well-developed porosity with a super-high specific surface area (2638.09 m2 g-1), abundant meso-/micropores (0.5-10 nm), high hydrophobicity, excellent thermal stability (>720 °C), and a partly graphitized structure. As a coating material for headspace-SPME, the MMC-coated fiber exhibited outstanding extraction capability for CBs (up to 48.5 times higher than that of commercial fibers), which may be attributed to multiple interactions between the MMC and the pollutants, including size selectivity, micropore filling, π-π stacking and hydrophobicity. Finally, a satisfactory method using an MMC-coated fiber coupled with gas chromatography and electron capture detection was developed with good linearity (1-1000 ng L-1, R2 > 0.9982), high enrichment efficiencies (enrichment factors, 861-7819), low limits of detection (0.003-0.072 ng L-1), excellent repeatability (0.7-5.3%) and reproducibility (1.7-5.1%), and outstanding recoveries (90.18-103.02%) when applied to determine trace CBs in real water samples. These results suggest that MMC is a promising coating material for the SPME of CBs.
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