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Geometry-induced interface pinning at completely wet walls
1Department of Physical Chemistry, University of Chemical Technology Prague, 166 28 Prague 6, Czech Republic and Department of Molecular and Mesoscopic Modelling, ICPF of the Czech Academy Sciences, 165 02 Prague 6, Czech Republic.
Abstract:
We study complete wetting of solid walls that are patterned by parallel nanogrooves of depth D and width L with a periodicity of 2L. The wall is formed of a material which interacts with the fluid via a long-range potential and exhibits first-order wetting transition at temperature T_{w}, should the wall be planar. Using a nonlocal density functional theory we show that at a fixed temperature T>T_{w} the process of complete wetting depends sensitively on two microscopic length scales L_{c}^{+} and L_{c}^{-}. If the corrugation parameter L is greater than L_{c}^{+}, the process is continuous similar to complete wetting on a planar wall. For L_{c}^{-}
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