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Investigating Electronic Communications in meso-meso Ethene-Bridged Unsymmetrical Diporphyrins
Anna Zieleniewska1, Dirk M Guldi1
1Department of Chemistry and Pharmacy, Friedrich-Alexander-University Erlangen-Nürnberg, 91058, Erlangen, Germany.
Abstract:
At the focal point of this work is the photophysical characterization of three meso-meso ethene-bridged diporphyrins featuring a diverse metallation pattern. Detailed investigations by means of cyclic voltammetry, absorption, fluorescence, and femto-/nanosecond transient absorption spectroscopy revealed the impact of open-shell nickel(II) on the electronic communication in ethene-bridged heterobimetallic diporphyrins.
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