Blue Laser Projection Printing of Conductive Complex 2D and 3D Metallic Structures from Photosensitive Precursors

Photosensitive precursors are developed for the printing of 2D and 3D conductive structures via blue laser projection printing. With the assistance of a photosensitizer, metal nanoparticles can be efficiently photosynthesized under laser irradiation of low light intensity (45-290 mW cm^-2). By projecting well-defined laser patterns on the precursor, corresponding 2D metal structures with the finest line of about 50 μm can be formed on various substrates including flexible polymer thin films, curved substrates, and ground glass. Moreover, complex 3D objects with nanoparticles embedded in the polymeric matrix are constructed via 3D printing combining photoreduction of the metal precursor and photopolymerization of resin. The as-prepared structures exhibit promising conductivities after sintering (in the order of magnitude of 10⁶ S m^-1). A possible mechanism of photochemical synthesis of metal nanoparticles upon exposure to blue laser is proposed. The high efficiency and low cost of the technique, the complexity of the structures prepared, and the applicability to various substrates and metals (including silver, gold, and palladium) promise practical applications of this approach in the printed electronics industry.