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General theory of charge regulation within the Poisson-Boltzmann framework: Study of a sticky-charged wall model
1Department of Chemistry, Federico Santa Maria Technical University, Campus San Joaquin, Santiago, Chile.
Abstract:
This work introduces a sticky-charge wall model as a simple and intuitive representation of charge regulation. Implemented within the mean-field level of description, the model modifies the boundary conditions without affecting the underlying Poisson-Boltzmann (PB) equation of an electrolyte. Employing various modified PB equations, we are able to assess how various structural details of an electrolyte influence charge regulation.
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