Mixed matrix membrane contactor containing core-shell hierarchical Cu@4A filler for efficient SO₂ capture

Achieving high flux membrane contactor is significantly important for hazardous gas removal. In this study, we prepared poly(vinylidene fluoride) (PVDF)-based mixed matrix membrane contactor (MMMC) that contained a core-shell hirarchical Cu@4A composite filler (Cu@4A). On one hand, the Cu@4A regulated the physical structure of MMMC, which enhanced gas permeation and thus resulted in the increment of physical SO₂ absorption flux. On the other hand, Cu@4A changed the chemical environment of MMMC by remarkably increased SO₂ facilitated transport sites, which elevated SO₂ concentration around Cu@4A by the enhancement of adsorption and oxidation of SO₂, resulting in the increase of chemical SO₂ absorption flux. Moreover, the copper nanosheets on 4A helped to construct facilitated transport pathways along the Cu@4A fillers at polymer-filler interface. The results showed that Cu@4A loaded MMMC exhibited increased SO₂ removal efficiency and SO₂ absorption flux compared with PVDF control membrane. Specifically, the M₁₀⁴⁰ MMMC loaded with 40 wt% Cu@4A and PVDF concentration 10 wt% exhibited the highest SO₂ removal efficiency and SO₂ absorption flux, which was up to 73.6% and 9.1 × 10^-4 mol·m^-2·s^-1 at the liquid flow rate of 30 L/h. Besides, the overall SO₂ mass transfer coefficient (K_o) and membrane mass transfer resistance (H/K_m) were investigated.