Related Experiment Video
Updated: Jan 24, 2026

Two-way Valorization of Blast Furnace Slag: Synthesis of Precipitated Calcium Carbonate and Zeolitic Heavy Metal Adsorbent
Published on: February 21, 2017
Synergetic Effect of Ultrasmall Metal Clusters and Zeolites Promoting Hydrogen Generation
Qiming Sun1, Ning Wang1, Risheng Bai1
1State Key Laboratory of Inorganic Synthesis and Preparative Chemistry College of Chemistry Jilin University 2699 Qianjin Street Changchun 130012 P. R. China.
Abstract:
Taking advantage of the synergetic effect of confined ultrasmall metal clusters and zeolite frameworks is an efficient strategy for improving the catalytic performance of metal nanocatalysts. Herein, it is demonstrated that the synergetic effect of ultrasmall ruthenium (Ru) clusters and intrinsic Brønsted acidity of zeolite frameworks can significantly promote the hydrogen generation of ammonia borane (AB) hydrolysis. Ultrasmall Ru clusters are embedded onto the silicoaluminophosphate SAPO-34 (CHA) and various aluminosilicate zeolites (MFI, *BEA, and FAU) with tunable acidities by a facile incipient wetness impregnation method. Evidenced by high-resolution scanning transmission electron microscopy, the sub-nanometric Ru clusters are uniformly distributed throughout the zeolite crystals. The X-ray absorption spectroscopy measurements reveal the existence of Ru-H species between Ru clusters and adjacent Brønsted acid sites of zeolites, which could synergistically activate AB and water molecules, significantly enhancing the hydrogen evolution rate of AB hydrolysis. Notably, the Ru/SAPO-34-0.8Si (Si/Al = 0.8) and Ru/FAU (Si/Al = 30) catalysts with strong acidities afford high turnover frequency values up to 490 and 627 min-1, respectively. These values are more than a 13-fold enhancement than that of the commercial Ru/C catalyst, and among the top level over other heterogeneous catalysts tested under similar conditions.
More Related Videos
05:52Resource Recycling of Red Soil to Synthesize Fe2O3/FAU-type Zeolite Composite Material for Heavy Metal Removal
Published on: June 2, 2022
08:40Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
Published on: December 6, 2021
Related Concept Videos
Alkali Metals
Table 1: Properties of the alkali metals
Hydrogen Bonds
Hydrogen Bonds Control the World!
Because hydrogen has very weak electronegativity when it binds with a strongly electronegative atom, such as oxygen or nitrogen, electrons in the bond are unequally shared....
Hydrogen Bonds
Bonding in Metals
The Eukaryotic Promoter Region
Metallic Solids
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....