CeO₂-Decorated ?-MnO₂ Nanotubes: A Highly Efficient and Regenerable Sorbent for Elemental Mercury Removal from...

CeO₂ nanoparticle-decorated ?-MnO₂ nanotubes (NTs) were prepared and tested for elemental mercury (Hg⁰) vapor removal in simulated natural gas mixtures at ambient conditions. The composition which had the largest surface area and a relative Ce/Mn atomic weight ratio of around 35% exhibited a maximum Hg⁰ uptake capacity exceeding 20 mg?g^?1 (2 wt %), as determined from measurements of mercury breakthrough which corresponded to 99.5% Hg⁰ removal efficiency over 96 h of exposure. This represents a significant improvement in the activity of pure metal oxides. Most importantly, the composite nanosorbent was repeatedly regenerated at 350 ?C and retained the 0.5% Hg⁰ breakthrough threshold. It was projected to be able to sustain 20 regeneration cycles, with the presence of acid gases, CO₂, and H₂S, not affecting its performance. This result is particularly important, considering that pure CeO₂ manifests rather poor activity for Hg⁰ removal at ambient conditions, and hence, a synergistic effect in the composite nanomaterial was observed. This possibly results from the addition of facile oxygen vacancy formation at ?-MnO₂ NTs and the increased amount of surface-adsorbed oxygen species.