Observation of ZrNb₁₄O₃₇ Nanowires as a Lithium Container via In Situ and Ex Situ Techniques for High-Performance...

Based on the high theoretical capacity and relatively high safety voltage, niobium-based oxides are regarded as promising intercalation-type electrode materials for advanced lithium-ion batteries (LIBs). Here, ZrNb₁₄O₃₇ nanowires are fabricated via a facile electrospinning method, presenting a nanoparticle-in-nanowire architecture. As an anode for LIBs, the as-fabricated ZrNb₁₄O₃₇ nanowires maintain a capacity of 244.9 mA h g^-1 at 100 mA g^-1 and present excellent cycling capability (0.026% of capacity fading per cycle during 1000 cycles) as well as outstanding rate performance. In situ X-ray diffraction measurement is conducted to understand the fundamental reaction mechanism during the lithiation/delithiation process. The ex situ observations, including X-ray photoelectron spectroscopy and transmission electron microscopy, are further performed to provide more lines of evidence of the reaction mechanism. Moreover, the excellent electrochemical performance of the full cell constructed using ZrNb₁₄O₃₇ nanowires and LiCoO₂ suggests that ZrNb₁₄O₃₇ nanowires are a promising anode material. This work sheds new light on understanding the lithium storage mechanism and may open new opportunities to develop new anode materials for LIBs.