Vapor-Phase Deposition and Electronic Characterization of 3-Aminopropyltriethoxysilane Self-Assembled Monolayers on...

Although organosilanes, especially 3-aminopropyltriethoxysilane (APTES), are commonly used to functionalize oxide substrates for a variety of applications ranging from molecular/biosensors and electronics to protective layers, reliable and controlled deposition of these molecules remains a major obstacle. In this study, we use surface potential analyses to record and optimize the gas-phase deposition of APTES self-assembled monolayers (SAMs) and to determine the resulting change of the electrokinetic potential and charge at the solid?liquid interface when the system is exposed to an electrolyte. Using a gas-phase molecular layer deposition setup with an in situ molecule deposition sensor, APTES is deposited at room temperature onto ozone-activated SiO₂. The resulting layers are characterized using various techniques ranging from contact angle analysis, ellipsometry, fluorescence microscopy, X-ray photoelectron spectroscopy, and electrokinetic analysis to AFM. It turns out that adequate postdeposition treatment is crucial to the formation of perfect molecular SAMs. We demonstrate how a thick layer of APTES molecules is initially adsorbed at the surface; however, the molecules do not bind to SiO₂ and are removed if the film is exposed to an electrolyte. Only if the film is kept in a gaseous environment (preferable at low pressure) for a long enough time do APTES molecules start to bind to the surface and form the SAM layer. During this time, superfluous molecules are removed. The resulting modification of the electrokinetic potential at the surface is analyzed in detail for different states.