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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
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Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
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Solution Composition During Acid/Base Titrations01:17

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The titration of a weak acid with a strong base results in the formation of water and the conjugate base of the acid. For instance, titrating acetic acid with sodium hydroxide leads to the formation of water and sodium acetate. A solution of acetic acid and sodium acetate constitutes a buffer whose relative concentration at different stages of the titration is indicated by the α values, which represent percentages of the weak acid and its conjugate base.
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Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
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Thiols and sulfides are sulfur analogs of alcohols and ethers, respectively, where the sulfur atom takes the place of the oxygen atom. Thus, thiols are generally represented as RSH, where R is an alkyl substituent and —SH is the functional group. On the other hand, in sulfides, the central sulfur atom is bonded to two hydrocarbon groups on either side. Depending upon the type of group, sulfides can be either symmetrical or asymmetrical. Both thiols and sulfides display a bent geometry,...
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Structures of Solids02:22

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Solids in which the atoms, ions, or molecules are arranged in a definite repeating pattern are known as crystalline solids. Metals and ionic compounds typically form ordered, crystalline solids. A crystalline solid has a precise melting temperature because each atom or molecule of the same type is held in place with the same forces or energy. Amorphous solids or non-crystalline solids (or, sometimes, glasses) which lack an ordered internal structure and are randomly arranged. Substances that...
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Updated: Jan 24, 2026

Screening of Coatings for an All-Solid-State Battery Using In Situ Transmission Electron Microscopy
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Screening of Coatings for an All-Solid-State Battery Using In Situ Transmission Electron Microscopy

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Cathode coating using LiInO2-LiI composite for stable sulfide-based all-solid-state batteries.

Hwan Wook Kwak1, Yong Joon Park2

  • 1Department of Advanced Materials Engineering, Kyonggi University, 154-42, Gwanggyosan-Ro, Yeongtong-Gu, Suwon-Si, Gyeonggi-Do, 16227, Republic of Korea.

Scientific Reports
|June 1, 2019
PubMed
Summary
This summary is machine-generated.

Introducing LiInO2-LiI cathode coatings enhances all-solid-state battery stability by suppressing interfacial reactions. This novel approach improves electrochemical performance and safety for next-generation energy storage.

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Energy Storage

Background:

  • All-solid-state batteries (ASSBs) offer enhanced safety over conventional lithium-ion batteries by utilizing inorganic solid electrolytes, eliminating flammable organic components.
  • Sulfide-based solid electrolytes exhibit high ionic conductivity and mechanical flexibility, making them promising candidates for ASSBs.
  • A significant challenge remains the interfacial instability between sulfide electrolytes and oxide cathodes, such as Li[Ni0.8Co0.15Al0.05]O2, leading to performance degradation.

Purpose of the Study:

  • To develop and evaluate novel cathode coating materials to mitigate interfacial reactions in sulfide-based ASSBs.
  • To investigate the efficacy of lithium indium oxide (LiInO2) and a LiInO2-lithium iodide (LiInO2-LiI) composite as protective layers for oxide cathodes.
  • To assess the impact of these coatings on the electrochemical properties and stability of the cathode-electrolyte interface.

Main Methods:

  • Synthesis and characterization of LiInO2 and LiInO2-LiI composite coating materials.
  • Application of coating layers onto Li[Ni0.8Co0.15Al0.05]O2 cathodes.
  • Fabrication and electrochemical testing of all-solid-state cells incorporating coated and pristine cathodes.
  • Analysis of interfacial reactions and ion diffusion using electrochemical impedance spectroscopy and other relevant techniques.

Main Results:

  • The LiInO2-LiI composite coating effectively suppressed undesirable interfacial reactions at the cathode/electrolyte interface.
  • The coating prevented the diffusion of sulfur and phosphorus ions from the sulfide electrolyte into the oxide cathode.
  • LiInO2-LiI coated electrodes demonstrated improved rate capability and reduced interfacial impedance compared to pristine and LiInO2-coated electrodes.
  • Electrochemical performance of the all-solid-state cells was significantly enhanced by the LiInO2-LiI cathode coating.

Conclusions:

  • LiInO2-LiI serves as an effective composite coating material for stabilizing the cathode-electrolyte interface in sulfide-based all-solid-state batteries.
  • This coating strategy successfully enhances the stability and electrochemical properties of oxide cathodes.
  • The findings highlight a promising pathway for developing high-performance and safe all-solid-state batteries.