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Updated: Jan 24, 2026

Synthesis and Catalytic Performance of Gold Intercalated in the Walls of Mesoporous Silica
Published on: July 9, 2015
Efficient CO2 Hydrogenation to Formate with Immobilized Ir-Catalysts Based on Mesoporous Silica Beads
Hung-Kun Lo1, Indre Thiel1, Christophe Copéret1
1Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir Prelog Weg 1-5, CH-8093, Zurich, Switzerland.
Abstract:
The Nozaki Ir-based CO2 hydrogenation catalyst was successfully immobilized on post-functionalized silica beads (d=200 μm) through click chemistry. This material hydrogenates CO2 into formic acid with turnover numbers reaching 2.8×104 in a batch reactor within 24 hours, paving the way towards the design of efficient heterogeneous catalysts for this transformation.
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