Related Experiment Video
Updated: Jan 24, 2026

A Triple Culture Cell System Modeling the Human Blood-Brain Barrier
Published on: November 30, 2021
Metal-Free Transfer Hydrobromination of C-C Triple Bonds
Weiqiang Chen1, Martin Oestreich1
1Institut für Chemie , Technische Universität Berlin , Strasse des 17. Juni 115 , 10623 Berlin , Germany.
Abstract:
A transfer hydrobromination of C-C triple bonds inititated by Brønsted acids is reported. Hydrogen bromide is released stepwise from a bench-stable cyclohexa-1,4-diene-based surrogate, generating biphenyl and ethylene as waste. A range of vinyl bromides was prepared from terminal and internal, mainly acceptor-substituted alkynes with good functional-group tolerance.
Related Concept Videos
Bonding in Metals
Metal-Ligand Bonds
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
Ionic Bonding and Electron Transfer
Bond Energies and Bond Lengths
Covalent Bonding and Lewis Structures
Types of Chemical Bonds

