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Updated: Jan 24, 2026

Negative Additive Manufacturing of Complex Shaped Boron Carbides
Published on: September 18, 2018
Reversible addition and hydrogenation of 1,1-diphenylethylene with a barium complex
1State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, No. 5625, Renmin Street, Changchun 130022, China. jhcheng@ciac.ac.cn.
Abstract:
Treatment of the barium hydride complex [(TpAd,iPr)Ba(μ-H)]2 (TpAd,iPr = hydrotris(3-adamantyl-5-isopropyl-pyrazolyl)borate) (1) with an excess amount of 1,1-diphenylethylene (DPE) afforded the corresponding mono-DPE adduct [(TpAd,iPr)Ba(η6-Ph)C(Ph)Me] (2) and di-DPE adduct [(TpAd,iPr)Ba(η6-Ph)C(Ph)-CH2-C(Ph)2Me] (3), which could convert to each other through a reversible equilibrium reaction. Complex 1 catalysed DPE hydrogenation under mild conditions (30 °C, 6 atm, 5 mol% cat.).
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