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Published on: September 2, 2008
[Ba13Sb36Cl34O54]8-: high-nuclearity cluster for the assembly of nanocluster-based compounds
Zhao-Feng Wu1, Bing Hu2, Zhi-Hua Fu2
1State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China. hubing@fjirsm.ac.cn xyhuang@fjirsm.ac.cn and Department of Chemistry and Chemical Biology, Rutgers University, 610 Taylor Road, Piscataway, NJ 08854, USA. jingli@rutgers.edu.
Abstract:
Herein, we report two nanocluster-based compounds built on an unprecedented cluster [Ba13Sb36Cl34O54]8-, which represents the first example of a discrete alkaline earth (AE)-containing oxochloride cluster and the largest Sb-based oxohalide cluster to date; the proton-conducting property of the compounds was investigated.
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