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Updated: Jan 23, 2026

Influence of Hybrid Perovskite Fabrication Methods on Film Formation, Electronic Structure, and Solar Cell Performance
Published on: February 27, 2017
Stepwise topochemical fluorination of SrCrO3 perovskite via a super-structured oxide
Yu Su1, Yoshihiro Tsujimoto2, Kotaro Fujii3
1Research Center for Functional Materials, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan. TSUJIMOTO.Yoshihiro@nims.go.jp.
Abstract:
A topochemical reaction between SrCrO3 and polyvinylydene fluoride yields the new fluorinated phase SrCrO2.8F0.2. The transformation proceeds via a reduced oxide intermediate (SrCrO2.8) that can be isolated as a single phase by the reaction between SrCrO3 and g-C3N4. The fluoride ions randomly occupy anion sites despite an oxygen-vacancy ordered structure in SrCrO2.8.
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